Apatite-forming ability of titania gels with different structures

摘要

It was already revealed that a sol-gel-derived titania forms an apatite on its surface in a simulated body fluid (SBF). It is, however, not clear what structure of titania gel is effective for inducing apatite nucleation on its surface. In the present study, apatite-forming ability of titania gels with different structures, which were formed in different media and heat-treated at different temperatures, were investigated in SBF. The titania gels heat-treated at 300 deg C took amorphous phases and did not form the apatite on their surfaces even after 14 days irrespective of the media. The titania gels, which were prepared in media containing no additive or acetylacetone and heat-treated at 500 to 800 deg C to precipitate anatase, formed the apatite on their surfaces within 7 days in SBF. The titania gels, which were prepared in a medium containing diethanolamine and heat-treated at 700 to 800 deg C to precipitate rutile, formed the apatite within 14 days in SBF. This indicates that a specific structure of titania such as anatase structure is effective for inducing apatite nucleation.