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TEST METHODS FOR DETERMINING ASPHALTENE STABILITY IN CRUDE OILS

机译:测定原油中沥青质稳定性的试验方法

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摘要

The high cost of remediating asphaltene deposition in crude oil production and processing has necessitated the development of test methods for determining the stability of asphaltenes in crude oils. In the current work, the stability of asphaltenes in crude oils of varying API gravity is predicted using the Oliensis Spot Test; two SARA-based tests; and a solvent titration method with NIR solids detection. The test methods are described in detail and experimental data from them presented. The experimental stability data were validated via correlation with data on the deposition histories of the oils. The effectiveness of the various tests as predictors of the stability of asphaltenes in oils is discussed. The Colloidal Instability Index and the solvent titration methods were found to predict a crude oil's propensity towards asphaltene precipitation better than both the Asphaltene-Resin ratio and the Oliensis Spot Test. For oils with low asphaltene content where most stability tests fail, live oil depressurization is proposed as the test for predicting the stability of asphaltenes.
机译:在原油生产和加工中补救沥青质沉积的高成本使得必须开发确定原油中沥青质稳定性的测试方法。在目前的工作中,使用Oliensis Spot Test预测了API重力变化的原油中沥青质的稳定性。两次基于SARA的测试;以及带有NIR固体检测的溶剂滴定法。详细描述了测试方法,并提供了来自这些测试方法的实验数据。通过与油的沉积历史数据的相关性验证了实验稳定性数据。讨论了各种测试作为预测油中沥青质稳定性的有效性。发现胶体不稳定性指数和溶剂滴定方法可以预测原油对沥青质沉淀的倾向,优于沥青质-树脂比和Oliensis点试验。对于大多数稳定性测试均未通过的低沥青质含量的油,建议使用活性油减压作为预测沥青质稳定性的测试。

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